Thursday, January 16, 2020

Getting Steely

To say that the bedrock of our society is steel would not be an understatement.  We use steel everyday in one or another way.

Understanding steel can be complicated, but we can get the basic ideas without too much pain.  Here’s the first part:  Steel is an alloy of the elements iron and carbon.

blade types, blade properties

Steel making starts with rust; different iron oxides are collected and heated with carbon to reduce the iron oxide to metal. I can imagine primitive man poking through the remnant of a camp fire looking for embers and finding something very different.

Two of the earliest forms were wrought and cast iron.  Both are crude, slag loaded, high carbon content forms of steel.  They still have roles to play in modern society.

Modern steel has from 0.05 to 2.1% carbon, and this is the core idea behind modern steels.  Molten iron can in fact dissolve more carbon than it can keep suspended in solid form.  Depending on how much is present and how fast the metal cools, wondrous things happen.  One is the formation of iron carbides.  These are very small, very hard pieces of grit that help strengthen steel.  Other elements form even better carbides, like chromium or vanadium.

The second part we need to understand is the formation of three different arrangements of iron and carbon.  These are ferrite, austenite and martensite.

Ferrite has the least tolerance for carbon in the crystalline solid.  Austenite has a slightly different crystal structure and slightly higher tolerance.  Martensite holds even more carbon, but it is forced to drastically change its size and shape of its crystal habit. 
Each of the three arrangements has different physical properties.

Heat treatment relies on an understating of how the steel alloy changes with temperature, cooling rates, cycling rates and trace elements.  This process involves complicated heating, cooling, annealing and aging steps.  Don’t believe everything you see on Forged in Fire about quenching red hot steel.  Quite a few steps are left out.  Here’s a rather simple annealing and tempering process
Heat to 1600F(870C), hold 2 hours, slow cool 30F (15C)/hour maximum to 1000F(540C), then air or furnace cool. Hardness BHN 225/255.  Followed by tempering: Heat to 1000F(540C) minimum recommended. Double tempering required and triple tempering recommended when hardening from 2100F(1150C) or higher. Air cool to room temperature between tempers.

Steel is a dynamic, evolving product and any list is almost assured to be incomplete.  Not every steel is suitable for making blades.  Types of steel used by different manufacturers are subject to change without informing me.  In fact, much of this information about steels currently in use by specific manufacturers is wrong.

Lastly, steel formulas are given as percentage of alloying elements.  The actual percent iron is calculated by difference.

5160, a spring steel, popular  for forging swords and large knives.  High toughness and good wear resistance.  Popular sword manufacturers that use 5160 spring steel are Hanwei Forge and Generation 2. 5160 spring steel is mainly used on medieval type swords.
6150, a chromium-vanadium alloy. Similar to 4140, 6150 is a tough steel with good impact resistance that can be hardened to the mid-50s on the HRC scale. While a good material for swords or tomahawks, it is less than ideal for most knives because of its limited attainable hardness.  
V-toku1 / V-toku2, alloyed steel with W /Cr's original characteristics.

Tool steels
Tool steel grades used in cutlery are: A, D, O, M, T, S, L, W.
A2 is a steel that trades wear resistance for toughness. It is used in custom made fighting knives by makers such as Phill Hartsfield, Rob Criswell, Mike Snody and John Fitzen (Razor Edge US) and one of the latest to standardize his camp/survival knives in A2 tool steel is Aaron Gough from Gough custom, Canada.  A2 was the standard baseline steel used by Bark River Custom Knives. A2 is used as the standard tool steel for Black Wolf Knives range of Hunting Knives by Marc Godwin, Japan
A6, this grade of tool steel air-hardens at a relatively low temperature (approximately the same temperature as oil-hardening grades) and is dimensionally stable. Therefore, it is commonly used for dies, forming tools, and gauges that do not require extreme wear resistance but do need high stability.
A8, C 0.55% Mn 0.30% Si 0.30% Cr 5.00% Mo 1.25% W 1.25%
A10, this grade contains a uniform distribution of graphite particles to increase machinability and provide self-lubricating properties. It is commonly used for gauges, arbors, shears, and punches.
D2, is a high carbon, high chromium die steel and is the highest carbon alloy tool and die steel typically used in knife making.  With a chrome content of 12.00%, some call it a "semi-stainless", because of the lack of free chromium, (as compared to the chromium reacted to form chromium carbides), even though it is defined by ASM and ANSI as stainless which contains at least 11.5% by weight of chromium.  It deserves the informal myth: "D2 knives hold an edge forever, and are impossible to sharpen."  While not as tough as premium carbon steels, it is much tougher than premium stainless steels.  D2 knife blades were popularized by Jimmy Lile, and later by Bob Dozier.
O1, a popular forging steel. Good wear resistance and excellent edge retention. It is a very tough, but not as much as 5160.  It is most commonly used by Randall Knives, Mad Dog Knives, and many other custom knife makers.
M2, is slightly tougher than D-2. As a high speed tool steel, it is capable of keeping a tempered edge at high temperatures generated in various machining processes. However, it isn't used as widely in factory production knives, as CPM M4 has become more popular. Custom knife makers still use it for knives intended for fine cutting with very thin edges.
M4, see High speed CPM REX M4.
S1, a shock-resistant medium carbon tool steel which combines moderate hardness with good impact toughness. Carbon content 0.40 - 0.55%.
S7, a shock-resistant medium carbon tool steel, with outstanding impact toughness and high strength, along with medium wear resistance. It has maximum shock resistance and high compression strength, which gives it good deformation resistance in use, while retaining good toughness.
W1, a water hardening tool steel. High carbon content.
W2, a tool steel that holds its edge quite well but not very tough. Has a carbon content of 1.5.  Most readily available W2 has a carbon content of no more than 1-1.1%. It can be left at high hardness levels (it can attain a quenched hardness of 67 Rc) and still be quite tough especially in larger knives with thicker spines as the core of the thick portion of the blade does not attain full hardness because of the shallow hardening nature of the steel. Bill Moran considered it to be almost as tough as 5160, but it was unavailable for a period of time. W2 is one of the carbon steels that can produce a nice Hamon in heat treating.
SK3, SK4, SK5 - Japanese carbon steels. SK stands for "Steel Kougu" meaning "Steel Tool". The lower number indicates fewer impurities.

CPM Tool Steel  Crucible Industries produces Crucible Particle Metallurgy (CPM) tool steels using a powder metal forge process.
CPM 1V, a proprietary steel, very high toughness, several times higher than A2 with same level of wear resistance.
CPM 3V is a proprietary steel, very high toughness, less than CPM 1V, but more than A2, and high wear resistance, better than CPM 1V. Used by several custom knives makers and factories, including Jerry Hossom, Mike Stewart [Bark River], Reese Weiland, Nathan Carothers, and Dan Keffeler. Makes good choice for swords and large knives.
CPM 4V a proprietary steel, high-impact toughness and a very good wear resistance. Gaining popularity in Bladesports Competition Cutting knives.
CPM 9V,a modification of CPM 10V with lower carbon and vanadium to improve toughness and heat check resistance.
CPM 10V (AISI A11), highly wear-resistant tool steel, toughness comparable with D2 tool steel. Currently used by a few custom knife makers, including Christopher "Big Chris" Berry. Phil Wilson pioneered the use of CPM 10V and numerous other CPM steels in sporting knives.
CPM 15V, a proprietary steel, extremely high wear-resistant tool steel, thanks to 14.5% Vanadium content. Found only in custom knives.
CPM CRU-WEAR, a proprietary steel designed as a CPM upgrade to conventional Cru-Wear and D2 steels, it offers better wear resistance, toughness, and hardness.
CPM REX M4 is a special purpose high speed steel designed to give high wear resistance in tools. Its high vanadium and carbon content provide for superior resistance to cratering and wear, exhibiting better wear resistance than M2 or M3.  C 1.30%, Cr 4.00%, W 5.50%, V 4.00% and Mo 4.50%.

Chrome steel
Chrome steel is one of a class of non stainless steels which are used for applications such as bearings, tools and drills.
AISI 52100, ball bearing steel. In terms of wear resistance, a little better than that of the O1 steel, however 52100 is also tougher. It has very fine carbides, which translates into high edge stability. Used by many custom makers, Swamp Rat knives uses 52100 steel under the name SR101.  Also referred to as 100 Cr 6/102 Cr6 as per ISO nomenclature and conforms to BS grade En31.
SUJ2, Japanese equivalent to AISI 52100 steel.

Semi-stainless steels
Steels that did not fit into the stainless category because they may not have enough of a certain element, such as chromium.
V-Gin1, a fine-grained steel with Mo, V for the best effect of Cr.
V-Gin2, more Cr is added for better corrosion resistance.
V-Gin3B, more Cr is added for better corrosion resistance.

Stainless steel
Stainless steel is a popular class of material for knife blades because it resists corrosion and is easy to maintain. But stainless steels are not impervious to corrosion or rust.  In order for a steel to be considered stainless it must have a chromium content of at least 10.5%.
154CM / ATS-34 steels  These two steels are practically identical in composition. They were introduced into custom knives by Bob Loveless circa 1972.
154CM is produced by Crucible Industries. It was once used extensively by Benchmade Knife Company and many others. 
CPM 154 is identical to 154CM in composition, however it is produced by Crucible using CPM Process bringing all the benefits of Particle Metallurgy technology.
ATS-34 is produced by Hitachi Metals.
The latter two are considered premium cutlery steels for both folding knives and fixed blades.

400 series
The 400 series remains one of the most popular choices for knife makers because it is easy to sharpen and it is resistant to corrosion and is magnetic.
410 is a hardenable, straight-chromium stainless steel which combines superior wear resistance with excellent corrosion resistance.
416 is very similar to 410 with the addition of sulfur to improve machinability.
420 has more carbon than 410, but less than 440. As such it is softer than 440, but has a higher toughness.
420 series contain several types with various carbon content between 0.15% and 0.40%.  This steel grade is widely used to make high end razor blades, surgical scalpels etc. It obtains about 57 HRC after suitable heat treatment. 420HC (420C ) is a higher carbon content 420 stainless. The HC stands for "high carbon" and it can be brought to a higher hardness than regular 420 and should not be mistaken for it. Buck Knives and Gerber Knives use 420HC extensively. 420A ( 420J1 ) and 420B ( 420J2 ) are economical, highly corrosion resistant stainless steel grades. Knife manufacturers use this material in budget knives, also in diving knives due to its high resistance to corrosion.
440 series has three types, 440A, 440B and 440C. 440A is a relatively a low cost, highly corrosion resistant stainless steel. In China, Ahonest ChangJiang Stainless steel developed 440A modified 7Cr17MoV, by adding more element vanadium.  440B is almost identical to 440A, but has a higher carbon content range compared to 440A.  440C is considered a high-end stainless steel. It is very resistant to corrosion and is one of the most common stainless alloys used for knife making. The once ubiquitous American Buck Model 110 Folding Hunter was made of 440C before 1981. 440C has highest carbon content in 440 group.  Böhler n695 is equivalent to 440C. Knife blades specified as being "440" can typically be assumed to be the lower hardness 440A grade.

AUS series
The AUS stainless steel series is produced by Aichi Steel Corporation of Japan. They differ from the AISI 4xx series because they have vanadium added to them. Vanadium improves the wear resistance, toughness, and ease of sharpening.  In the alloy name the appended 'A' indicates the alloy has been annealed.
AUS-6 (6A) is comparable to 440A with a carbon content close to 0.65%. It is a low cost steel, slightly higher wear resistance compared to 420J.  A typical formula would be  C 0.6%, Cr 14%, V 0.17%
AUS-8 (8A) is comparable to 440B with a carbon content close to 0.75%.  AUS-8 is often used instead of 440C. SOG knives uses AUS-8 extensively.
AUS-10 is comparable to 440C with a carbon content close to 1.10%.  It is slightly tougher than 440C.

CPM SxxV series are Crucible Industries stainless steels produced using CPM process.

CPM S30V, on the lower end of the SxxV steels, it has a carbon content of 1.45%. However, S30V is still considered to be a superior choice for knife making. CPM S30V is used in a wide range of ZT knives.
CPM S35VN is a martensitic stainless steel designed to offer improved toughness over CPM S30V. It is also easier to machine and polish than CPM S30V. It is used in many high end kitchen knives including those by New West Knifemakers.
CPM S60V (formerly CPM T440V) (discontinued), very rich in vanadium. CPM S60V has a carbon content of 2.15%.  It was an uncommon steel, but both Spyderco and Kershaw Knives offered knives of this steel, Boker still offers folders made from CPM S60V.
CPM S90V (formerly CPM T420V) has less chromium than S60V, but has almost twice as much vanadium. S90V's carbon content is also higher, resting around 2.30%.
CPM S110V has higher corrosion resistance than S90V and marginally better wear resistance. The additional corrosion resistance while retaining all the benefits of S90V makes this steel extremely desired for kitchen cutlery.
CPM S125V contains 3.25% carbon, 14% chromium and 12% Vanadium and other alloying elements.  Exceptionally high wear resistance, making it difficult to process and machine for knifemakers.  At first only used in custom knives, it has been utilized by larger manufacturers more recently in very limited quantities.

VG series Japanese stainless steels, manufactured by Takefu Special Steel.
VG-1, Takefu stainless steel. Popular steel in Japanese kitchen knives.  C 1%, Cr 13.0-15.0 %, Mo 0.3 %. During forging, Mo and Cr form hard double carbide bonds, which help improve the abrasion and corrosion resistance of the steel.
VG-2, middle-carbon Mo stainless blade steel.
VG-5, synergic effect of Mo and V makes carbide finer.
VG-7/VG-8W, strengthens substrate and improves tempering performance.
VG-10(B/W), Takefu stainless steel, similar composition to VG-1 but also contains cobalt and vanadium. Good wear resistance and rust resistance.
Due to small Vanadium content VG-10 has finer grain content compared to VG-1. Cobalt and Nickel improve toughness. Overall, it has better edge stability compared to VG-1. VG-10 is widely used in Japanese kitchen knives, several manufacturers use it in various folders and fixed blade knives, including Spyderco, Cold Steel and Fallkniven.
San-mai, A composite steel used to make high end knives. The core is VG-1 and the outside layers are 420j for good rust resistance.  San-mai is also the term applied to a sandwich of a core steel with a different, usually softer, steel on both sides.

CTS series American stainless steels produced by Carpenter Technology using vacuum melt technology.
CTS-BD1, is a high-carbon chromium steel that provides stainless properties with high hardness and excellent wear resistance.
CTS-20(CP), offers superior edge retention and surface finish, an ability to be machined to a fine edge, and consistent heat-treatability from lot to lot.
CTS-40C(CP), a powder metallurgy, high-carbon chromium stainless steel designed to provide stainless properties with maximum hardness.
CTS-TMT, a hardenable martensitic stainless steel that combines improved corrosion resistance over Type 410 stainless with hardness up to 53 HRC and improved formability over 17Cr-4Ni.
CTS-XHP, a powder metallurgy, air-hardening, high carbon, high chromium, corrosion-resistant alloy. It can be considered either a high hardness 440C stainless steel or a corrosion-resistant D2 tool steel.
CrMo/CrMoV Series  Chinese and American stainless steels; the manufacturers are unknown with the exception of 14-4CrMo which is manufactured by Latrobe Specialty Metals.
(Sorted by first number.)
14-4CrMo, manufactured by Latrobe Specialty Metals. A wear resistant, martensitic stainless tool steel that exhibits better corrosion resistance than 440C stainless steel.
2Cr13, belongs to 420 grade series, very basic. EN 1.4021 / DIN X20Cr13, widely used in economic cutting tools, 50HRC max after heat treatment.
3Cr13, in 420 grade series, it contains 420A 420B 420C 420D. 3Cr13 steel is 420B, EN 1.4028 / DIN X30Cr13, 52HRC-ish after heat treatment.
3Cr13MoV, made by adding more elements molybdenum and vanadium to the 420J2-3Cr13 formula.
4Cr13, EN 1.4034 / DIN X46Cr13, 420C stainless steel, it obtains about 55-57HRC.
4Cr13Mo, EN 1.4419 / DIN X38CrMo14, developed based on GB 4Cr13 / DIN X46Cr13 by adding elements Molybdenum.
4Cr14MoV, EN 1.4117 / DIN X38CrMoV15, good enough to make kitchen knives.
5Cr15MoV, some knives manufacturers define as 5Cr13MoV, the hardness could be 55-57 HRC. It's widely used to make kitchen knives, high-end scissors, folding knives and hunting knives etc.
6Cr14MoV,The Patented name applied by Ahonest Changjiang Stainless steel Co., Ltd. Similar stainless steel grade 6Cr14 (6Cr13)/420D which does not contain molybdenum and vanadium used to make razor blades, surgical scalpels etc.
7Cr17MoV, 440A modified with more vanadium elements. The benefits of Vanadium: Increases strength, wear resistance, and increases toughness the recommended hardness about 55/57 HRC.
8Cr13MoV & 8Cr14MoV, similar to AICHI AUS-8, an excellent value priced steel for its performance.
9Cr13MoVCo, 9Cr14MoV. Chinese-made steels that are similar to 440B but with a higher carbon, cobalt and vanadium content to add more strength to the blade. Uses include high end barber scissors, hunting knives etc.
9Cr18MoV, 440B modified, a higher end Chinese stainless steel used mostly in high-end barbering scissors and surgical tools.
9Cr19MoV, used in items such as the Ultimate Pro Bear Grylls Survival knife.
99Cr18MoV, 440C modified. Developed by jaktkit and Ahonest Changjiang in cooperation. Uses ESR technology and hot forging. This improves its work performance, especially toughness, and edge holding ability.

Sandvik series
6C27, a common knife steel grade with good corrosion resistance and low hardness, mainly used in applications where the need for wear resistance is low.
7C27Mo2, Generally the same properties as Sandvik 6C27, but with improved corrosion resistance.
12C27, a grade with high hardness and good wear resistance. Takes very keen edge with moderate edge retention.
12C27M, another Swedish stainless razor steel. A very pure, fine grained alloy. A grade with good wear resistance and good corrosion resistance, well suited for the manufacture of kitchen tools.
13C26, also known as a Swedish stainless razor steel. Generally the same properties as Sandvik 12C27, but with slightly higher hardness but less corrosion resistant. The Swedish steel maker Uddeholm AB also makes a virtually identical razor steel composition known as AEB-L, which they patented in 1928. Swedish razor steel is a very pure, fine grained alloy which positively affects edge holding, edge stability and toughness.
14C28N, designed by Sandvik at Kershaw's behest to have the edge properties of 13C26 but with increased corrosion resistance by adding nitrogen and chromium.
19C27, a grade with very high hardness and wear resistance.

DSR series  Daido stainless tool steels used for kitchen knives and scissors.
DSR1K6(M), similar to AUS-6 and VG2
DSR7F, used for high-hardness cutting parts.
DSR10UA, used for small scissors.

High Chrome / High Vanadium Stainless  The following Powder Metallurgy steels contain very high levels of Chromium, which at 18%-20% produces a steel matrix that is highly corrosion resistant. They also contain relatively high levels of Vanadium (3.0% to 4.0%), producing a high volume of Vanadium-Carbides in the steel matrix, associated with excellent abrasion resistant edge holding.
M390 - Bohler M390 Microclean. Third-generation powder metallurgy technology steel. Developed for knife blades requiring good corrosion resistance and very high hardness for excellent wear resistance. Chromium, molybdenum, vanadium, and tungsten are added for excellent sharpness and edge retention. Can be polished to an extremely high finish. Hardens and tempers to 60-62 HRC, where it best balances edge holding and toughness. Due to its alloying concept, this steel offers extremely high wear resistance and high corrosion resistance.
CPM-20CV - essentially Crucible's version of M390.
CTS 204P - essentially Carpenter's version of M390.
Elmax - Produced by Bohler-Uddeholm, Elmax is a through-hardening corrosion resistant mold steel using third-generation powder metallurgy process. Often said to be superior to CPM S30V and CPM S35VN for edge retention and ease of sharpening.  Elmax is very similar to M390, CPM 20CV, and CTS 204P, but has somewhat lower Vanadium content, and lacks any Tungsten content.

Other stainless
ATS-55, produced by Hitachi Metals.[29] Has lower molybdenum content than ATS-34, is less wear-resistant than ATS-34 and has been reported to be also less rust-resistant than ATS-34.
BG-42 Slightly higher in carbon, chrome and moly than ATS-34. Must be forged and heat treated at very high and exact temperatures. Can be used at very high hardness, such as RC 64-66. Not supposed to be brittle, but high alloy steels usually are. Very expensive and hard to work. It is a martensitic stainless high speed steel that combines the tempering, hot hardness and hardness retention characteristics of M50 high speed steels, with the corrosion and oxidation resistance of Type 440C stainless. Although often used for aerospace bearings and other critical applications, its excellent wear resistance and corrosion resistance makes it a superior choice for use in cutlery applications.
Kin-2, Medium-carbon Mo, V stainless blade steel.
Cowry-X is produced by Daido steel using PM process. Contains 3% carbon, 20% chromium, 1.7% molybdenum and Less than 1.00% vanadium.  Other elements are not published or may not even exist. Used by Hattori knives in their kitchen knives KD series.
ZDP-189 is produced by Hitachi steel using PM (power metal) process. It contains 3% carbon and 20% chromium and contains tungsten and molybdenum.  Used by several custom knife makers and factory makers including Spyderco and Kershaw in the limited run of the Ken Onion Shallot folders. The Henckel Miyabi line markets this steel with the name "MC66".
R2 is a PM steel made by Kobe Steel Japan (Kobelco). It is also known as SG2 (Special Gold 2) when it is marked by Takefu Specialty Steel.
SRS-15 a High Speed Tool Steel (HSS) where the 15 represents 1.5% C. One of the earliest known Japanese "super steels" the maker is unknown. A SRS-13 with 1.3% C also exists.

High-speed steel
CPM REX series
CPM REX M4 HC (AISI M4) is a high speed tool steel produced by Crucible using CPM process. M4 has been around for a relatively long time, lately entering custom and high end production knives.  Popular steel for use in Bladesports Competition Cutting knives.
CPM REX 121 is a new high vanadium cobalt bearing tool steel designed to offer a combination of the highest wear resistance, attainable hardness, and red hardness available in a high-speed steel.[53]
CPM REX 20 (HS) is a cobalt-free super high speed steel made by the CPM process.
CPM REX 45 (HS) is an 8% cobalt modification of M3 high speed steel made by the CPM process. As of September 2018 this steel was used in some limited-run production knives from Spyderco.
CPM REX 54 HS is a cobalt-bearing high speed steel designed to offer an improvement in the red hardness of the popular M4 grade, while maintaining wear properties equivalent to M4.
CPM REX 66 (HSS)is a super high speed steel made by the CPM process.
CPM REX 76 (HSS) is a super high speed steel made by the CPM (Crucible Particle Metallurgy) Process. It is heat treatable to HRC 68-70. Its high carbon, vanadium and cobalt contents provide abrasion resistance comparable to that of T15 and red hardness superior to that of M42.
CPM REX 86 (HSS) is a super high speed steel made by the CPM process. It has a combination of high attainable hardness capability (68-70 HRC), red hardness, and abrasive wear resistance for difficult machining applications while still maintaining good fabricating and toughness characteristics. The composition is designed to provide a balance of vanadium-rich MC and tungsten-molybdenum-rich M6C primary carbides.
CPM REX T15(HSS) is a super high speed steel made by the CPM process. It is a tungsten type high speed containing high vanadium for excellent abrasion resistance, and cobalt for good red hardness, and is used for cutting difficult to machine materials where high frictional heating is encountered.
Maxamet is marketed by its manufacturer as a middle-ground between high-speed steel and cemented carbide. Carpenter claims Maxamet has improved hardness and wear resistance over high-speed steels while being tougher than cemented carbides. As of early 2018, it is used in several production knives from Spyderco.

Super stainless steels
The steels in this category have much higher resistance to elements and corrosion than conventional stainless steels. These steels are austenitic and non-magnetic. They are used in knives designed for use in aggressive, highly corrosive environments, such as saltwater, and areas with high humidity like tropical forests, swamps, etc. These steels can contain 26% to 42% chromium as well as 10% to 22% nickel and 1.5 to 10% of titanium, tantalum, vanadium, niobium, aluminum silicon, copper, or molybdenum etc., or some combination thereof.
H1, produced by Myodo Metals, Japan. Used by Spyderco in their salt water/diving knives. Benchmade used it as well, later replaced with X15TN.
X15Tn, French steel patented by Aubert&Duval, originally designed for medical industry and jet ball bearings . This is a Martensitic stainless steel, with a high nitrogen content, remelted for optimum structure and properties. Used by Benchmade in their salt water/diving knives.
N680, Bohler-Uddeholm steel , is also a Martensitic stainless steel, very similar to X15TN. Used by Benchmade in their salt water/diving knives.
N690CO an Austrian stainless steel hardened to the high Rc50 range. Currently found in Spyderco's Hossom knives and the recently discontinued Italian-made Volpe. TOPS knives also used it in their C.Q.T magnum 711 knife. Also used extensively by Fox Knives Military Division, Extrema Ratio and Steel Will Knives.
Vanax, produced by Uddeholm, is a relatively new, 3rd generation powder metallurgy blade steel in which carbon is largely replaced by nitrogen. This results in a steel with extreme corrosion resistance, excellent edge holding, yet it is fairly easily resharpened while containing a relatively high carbide volume for abrasive cutting edge retention.
LC200N (aka Z-FiNit) produced by Zapp Precision Metals, is a high nitrogen alloyed tool steel which exhibits superior corrosion resistance combined with high toughness even at hardness up to 60 HRc. Spyderco uses this steel in several of their knives.

Carbon steel is a popular choice for rough use knives. Carbon steel used to be much tougher, much more durable, and easier to sharpen than stainless steel.  This is no longer true.  Carbon steels lack the chromium content of stainless steel, making them susceptible to corrosion. They have less carbon than typical stainless steels do, but it is the main alloy element. They are more homogeneous than stainless and other high alloy steels, having iron carbide as the sole grain stabilizer. The bulk material is harder than stainless, allowing them to hold a sharper and more acute edge.  But they dull quicker because they lack sufficient hard carbides to prevent crystal deformation and slipping. This also makes them quicker to sharpen. Carbon steel is well known to take a sharper edge than stainless.

10xx series is the most popular choice for carbon steel used in knives as well as katanas. They can take and keep a very sharp edge.  XX represents the approximate carbon content in parts per hundred.

1095, a popular high-carbon steel for knives; it is harder but more brittle than lower carbon steels such as 1055, 1060, 1070, and 1080. It has a carbon content of 0.90-1.03%.  Many older pocket knives and kitchen knives were made of 1095. It is still popular with many bushcrafters and survivalists due to its toughness and ease of sharpening.  With a good heat treat, the high carbon 1095 and O-1 tool steels can make excellent knives.
1084, carbon content 0.80-0.93%. Often recommended for novice knife makers or those without more advanced heat treating equipment due to the ease of heat treating it successfully in such conditions, yet also used by many professional bladesmiths for various kinds of knives as it can make excellent knives.
1070, carbon content 0.65-0.75%.  Used in machetes.
1060, used in swords. It has a carbon content of 0.55-0.65%
1055, used in swords and machetes often heat-treated to a spring temper to reduce breakage. It has a carbon content of 0.48-0.55%

V-x series
V-1/V-2 Chrome is added to improve quenching performance.
V-2C, Pure carbon steel, with impure substances completely removed.

Aogami/Blue-Series a Japanese exotic, high-end steel made by Hitachi. The "Blue" or “White” refers to, not the color of the steel itself, but the color of the paper in which the raw steel comes wrapped.  They typically have low levels of impurities;
Aogami/Blue-Num-1 steel with higher tensile strength and sharpening ability than blue-2.
Aogami/Blue-Num-2  steel with higher toughness and wear resistance than blue-1.
Aogami/Blue-Super  steel with higher toughness, tensile strength and edge stability than all other steels in its series.
Aogami/Super blue The same steel as Blue-Super A, with  C 1..45 %, Cr 0.4%, W 2.25%, Mo 0.4. V 0.5 %
Shirogami/White-series( Again the color of the paper the raw steel is wrapped in.)
Shirogami/White-1 Hardest among the Hitachi steels, but lacks of toughness.
Shirogami/White-2 Tougher than S/W-1 but as not much carbon content, thus slightly less hard.
Kigami/Yellow-Series Steel "Better" steel compared to SK series, but worse than both, Aogami and Shirogami. Used in high end tools and low/mid class kitchen knives.

Other proprietary steels
INFI, an unique steel used in Busse knives. It is a tough steel, which resists both wear and corrosion relatively well. Prior to 2002, INFI contained 0.5% carbon, 0.74% Nitrogen, about 1% Cobalt, and about 0.1% Nickel. In 2002, Busse changed the steel composition by removing Nitrogen, but added 0.63% Silicon for toughness, and the Cobalt and Nickel components were dropped.  One could ask is it really the same steel?

Other carbon steel  These steels are the WTF steels which did not exist in a series and are unique to themselves.

4116 Krupp is a German steel which is cryogenically quenched during the hardening process. Used in many entry level knives by Henkels, Wusthof and other German makers hardened to 54-56 RC. High stain resistance but mediocre edge retention. 0.45-0.55 carbon, .1-0.2 vanadium, 14-15 Chromium, 0.5-0.8 Molybdenum.  In 2017 it made inroads in mid priced (between 7Cr17Mov and 440C San Mai)
Acuto 440. manufactured by Aicihi Cr 0.80-0.95 Si 0.35-0.50 Mn 0.25-0.40 P under 0.040 S under 0.030 Cr 17.00-18.00 Mo 1.00-.25 V 0.08-0.12 contents.  (That makes that perfectly clear, doesn’t it!) This steel is specifically designed to meet resistance to corrosion and wear in stainlessAL-158
BRD4416 stainless steel.
X55CrMo14 or 1.41110 Swiss Army knife Inox blade steel used by Victorinox.

Did we miss a few steels?  Yes.  And I can assure you manufacturers have changed the steel they use in making your favorite knives.  Companies balance steel and manufacturing cost against market share.  Few of us would purchase what might literally be the best knife blade in existence if the cost was $1000, but we would buy a good knife blade for $68.


Wedgehead said...

Thanks for posting this Frank. I'm keeping it for future reference.

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Knife Analyst said...

Very helpful post Frank, I'll keep this for reference.